Cannot send mail from Outlook 2010 on my new MAC Air

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I am transitioning from PC to MAC. Downloaded Office Suite 365. Outlook works fine for incoming mail but cannot send mail. (it goes into my Outbox,) I have checked the settings, changed the default port 25 to 587, which is used successfully by my PC, and then to 465. Nothing has worked. Any ideas?
Hello [email protected], Thank you for contacting us today about problems sending mail from outlook. We are happy to help, but will need some additional information, since I could not locate an account on our servers. What domain are you trying to send email from? Have you reviewed your mail log for errors, or record of your transmissions? If you are on a shared server, Live support can assist you with this. Let us know if you have any further questions. Thank you, John-Paul